Published in Henry Rzepa's Blog

It is not only the non-classical norbornyl cation that has proved controversial in the past. A colleague mentioned at lunch (thanks Paul!) that tri-coordinate group 14 cations such as R 3 Si + have also had an interesting history.[cite]10.1021/ja990389u[/cite] Here I take a brief look at some of these systems. Their initial characterisations, as with the carbon analogues, was by 29 Si NMR.

References

General ChemistryCatalysisOrganic Chemistry

Reactions of Diaryldibromodisilenes with N‐Heterocyclic Carbenes: Formation of Formal Bis‐NHC Adducts of Silyliumylidene Cations

Published in Chemistry – A European Journal
Authors Tomohiro Agou, Naoki Hayakawa, Takahiro Sasamori, Tsukasa Matsuo, Daisuke Hashizume, Norihiro Tokitoh

AbstractReactions of stable 1,2‐dibromodisilenes ((E)‐Ar(Br)SiSi(Br)Ar) with N‐heterocyclic carbenes (NHC) afforded NHC–arylbromosilylene adducts or bromide salts of the corresponding bis‐NHC adducts of the formal arylsilyliumylidene cations ([ArSi:]+). In some cases, an NHC was able to replace a bromide anion in the coordination sphere of the arylbromosilylene–NHC adduct.