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Henry Rzepa's Blog

Henry Rzepa's Blog
Chemistry with a twist
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Cyclobutadiene is one of those small iconic molecules, the transience and instability of which was explained theoretically long before it was actually detected in 1965.[cite]10.1021/ja01092a049[/cite] Given that instability, I was intrigued as to how many crystal structures might have been reported for this ring system, along with the rather more stable congener cyclo-octatetraene. Here is what I found.

Published

A quartet of articles has recently appeared on the topic of cyclobutadiene.[cite]10.1002/chem.201102942[/cite],[cite]10.1002/chem.201103017[/cite],[cite]10.1002/chem.201203234[/cite],[cite]10.1002/chem.201203235[/cite]. You will find a great deal discussed there, but I can boil it down to this essence.

Published

Organic chemistry has some no-go areas, where few molecules dare venture. One of them is described by a concept known as anti-aromaticity. Whereas aromatic molecules are favoured species, their anti-equivalent is avoided. I previously illustrated this (Hückel rule) with cyclopropenium anion.